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Study Guides. Objectives After completing this section, you should be able to describe the physical significance of an orbital.
Key Terms Make certain that you can define, and use in context, the key terms below. The density of the dots is therefore greatest in the innermost shells of the onion.
Because the surface area of each shell increases more rapidly with increasing r than the electron probability density decreases, a plot of electron probability versus r the radial probability shows a peak. This peak corresponds to the most probable radius for the electron, Note the presence of circular regions, or nodes, where the probability density is zero. The cutaway drawings give partial views of the internal spherical nodes. The orange color corresponds to regions of space where the phase of the wave function is positive, and the blue color corresponds to regions of space where the phase of the wave function is negative.
They contain more nodes. This is similar to a standing wave that has regions of significant amplitude separated by nodes, points with zero amplitude. For a given atom, the s orbitals also become higher in energy as n increases because of their increased distance from the nucleus.
Contributors and Attributions Dr. Note that all three are spherically symmetrical. The minima correspond to spherical nodes regions of zero electron probability , which alternate with spherical regions of nonzero electron probability. Only s orbitals are spherically symmetrical. Because this orbital has two lobes of electron density arranged along the z axis, with an electron density of zero in the xy plane i.
Note that each p orbital has just one nodal plane. These subshells consist of seven f orbitals.
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